BMP testingStraws and crop residues

Tobacco stalks — BMP: 2 studies, weighted mean 139 m³ CH₄/t VS

Tobacco stalks are a lignocellulosic waste left after leaf harvest; raw stalks yield about 130-148 m³ CH₄/t VS in the literature, and clearly more only after pretreatment.

CH₄ ≈ 52 % (estimate)

Published Updated 4 min readFeedstockData Editorial Team

Photo Emw / Wikimedia Commons, licence CC BY-SA 3.0, source file; changes: cropping

Weighted mean
139m³ CH₄/t VS
Range
130–148m³ CH₄/t VS
Records
2studies
Publications
2sources
Temperatures
—of the test

Methane in biogas

Medium methane content · ≈ 5.2 kWh/m³ of biogas

estimate from the substrate type The collected studies contain no measurement. The interval follows from the approximate composition (carbohydrate-dominated (no protein or fat characteristics)) and the yields of compound groups according to FNR.

How we calculate it and what the zones mean

Rating for biogas plants

not rated — editorial rating for biogas plants

Not rated: no dry matter or volatile solids in the data. We calculate the rating when the dry matter and volatile solids of the material are known.

Editorial rating per the methodology

Add to the co-digestion calculator CSV data

BMP curves from 2 studies

Weighted mean Individual records

BMP curves: Tobacco stalksCumulative methane production over time for 2 records and the weighted mean of 139 m³ CH₄/t VS. 2 of the curves are model curves (first-order kinetics).050100150200051015202530time [d]m³ CH₄/t VSLi et al. (2019): 130 m³ CH₄/t VS (model curve)Zhang et al. (2020): 148 m³ CH₄/t VS (model curve)mean139

Dashed lines are a model curve (first-order kinetics, B(t) = B₀·(1 − e−kt)); the end point comes from the publication. All curves are model curves.

Cumulative methane production over the test [m³ CH₄/t VS]. The thick line is the weighted mean of all records (139); dots mark the end values given in the publications. Point at the chart to read values; click a legend item to hide or show a record.

Records and sources

Download CSV
SourceBMP
m³ CH₄/t VS
TemperatureSampleCurve
Li et al. (2019) DOI130—Nicotiana tabacum L. Yunyan114 (tobacco stalk)end point (model curve)
Zhang et al. (2020) DOI148—Tobacco stalk TS116 (untreated, OL 20.2 g VS/L, F/I 1.1)end point (model curve)
Weighted mean139arithmetic mean 139, SD 13

Process properties

  • fibrous
  • slowly degrading
  • seasonal
  • editorial classification

Advantages

  • Methane yield in the compendium: 130.2–148.1 m³ CH₄/t VS, 2 records from 2 papers (weighted mean 139.1).
  • Alkaline pretreatment with hydrogen peroxide (7% AHP) increased the yield of tobacco stalks by 105.6% to 350.7 m³ CH₄/t VS (biodegradability 81.4%) in a batch test (Zhang et al. 2020).
  • The digestate can be applied to arable land growing solanaceous crops: the CMV virus was inactivated under mesophilic and thermophilic conditions, and TMV only thermophilically after more than 20 days (Liu et al. 2015).

Drawbacks and risks

  • Low yield of raw stalks; varieties with a lower lignin content gave more methane (Li et al. 2019).
  • Lignocellulose recalcitrance limits digestion efficiency; pretreatment required (Wang et al. 2024).

Co-digestion — what to combine it with, what to watch out for

Dosing

No source-based limits on the share in the mix. Liu et al. (2015): the highest yield of tobacco stalks (0.163 m3 CH4/kg VS, VS removal 59.1%) was obtained in co-digestion with wheat straw and pig slurry at 35 °C. The literature in the abstracts checked gives no threshold for nicotine inhibition.

Introduce gradually, starting with a small dose and monitoring the process (e.g. FOS/TAC, pH, gas composition).

Practical requirements

  • Alkaline pretreatment with hydrogen peroxide (AHP) was the most effective of those tested (AHP, NaOH, KOH, Ca(OH)2, HCl, oxalic acid) (Zhang et al. 2020).
  • For digestate intended for solanaceous crops, use thermophilic digestion for at least 20 days, because TMV is not destroyed under mesophilic conditions (Liu et al. 2015).

The co-digestion calculator will assess a specific mixture containing this substrate.

What it is and where it comes from

Tobacco stalks (Nicotiana tabacum) are the lignified part of the plant that remains in the field or at the drying shed after the leaves are harvested. The largest quantities arise in China, where, according to the authors of the studies, this waste is a cause of serious environmental pollution when it is landfilled or burned. In Poland tobacco growing is small and regionally concentrated, so the stream is local in character. The compilation contains two records from two Chinese studies: stalks of the Yunyan114 variety (130.2 m³ CH₄/t VS; Li et al. 2019) and untreated TS116 stalks at the best loading and substrate-to-inoculum ratio (148.1 m³ CH₄/t VS; Zhang et al. 2020). The values come from publication abstracts.

Properties relevant to digestion

This is a typical lignocellulosic biomass. The authors of the first study compared four stalk varieties and indicated that the best result was obtained by the one with the lower lignin content, which confirms that it is lignin that limits the availability of cellulose to bacteria. The resistance of the lignocellulosic structure is also the main limitation identified in the study on microaerobic pretreatment of tobacco straw (Wang et al. 2024). Pretreatment has a clear effect: in the study by Zhang et al. (2020), of the tested methods (hydrogen peroxide in an alkaline medium, NaOH, KOH, Ca(OH)2, HCl, oxalic acid), the most effective was 7% alkaline hydrogen peroxide, which raised the yield by 105.6% to 350.7 m³ CH₄/t VS (biodegradability 81.4%). These values relate to material after treatment, so they are not counted among the records for the raw substrate.

How to read the spread of results

The two records come from two studies by the same team, but from different experiments and varieties, so the difference of 130-148 m³/t is consistent with the expected spread between varieties. The abstracts do not state the temperature or test duration for the records, and the Zhang et al. value is the best variant from a loading × S/I series, that is, an optimised result and not a typical one. For this reason the weighted average (about 139 m³/t) is only an indicative reference point. The result is also affected by the share of leaves and bark, the degree of shredding, the lignin content and the test length.

In biogas plant practice

Mono-digestion of raw stalks is unattractive because of the low yield. The highest result in co-digestion (0.163 m3 CH4/kg VS) was obtained with wheat straw and pig slurry at 35 °C, with a VS removal of the stalks of 59.1% (Liu et al. 2015). The same study shows an important hygiene issue: cucumber mosaic virus (CMV) was inactivated under both mesophilic and thermophilic conditions, whereas tobacco mosaic virus (TMV) was inactivated only in thermophilic digestion lasting more than 20 days. If the digestate is to be applied to solanaceous crops (e.g. potatoes, tomatoes), this must be taken into account. An own BMP test on the specific batch is necessary before design.

Methodology in brief

BMP is the amount of methane obtained from volatile solids (VS) in a batch test, given in m³ CH₄ per tonne of VS (numerically the same as NmL CH₄/g VS in the publications) and converted to normal conditions (0 °C, 101.325 kPa). The weighted mean gives each publication a total weight of 1, split equally between its results for the substrate — a paper testing twenty varieties does not outweigh a paper with a single sample. In inter-laboratory programmes the unit is the laboratory (total weight 1), and within it the weight of a test grows with the number of bottles (replicates). Results after pretreatment (e.g. thermal, chemical, enzymatic) are shown separately and are not included in the mean.

Solid lines are curves measured in the tests. Where a publication gives only the final result, we draw a first-order kinetic model, B(t) = B₀·(1 − e−kt): only the end point comes from the publication, and the shape of the curve serves purely as visualisation — do not read the production on a particular day from it. For this substrate k = 0.136 d−1 was assumed (median of rate constants k reported in the sources and/or fitted to the mean measured curves).

The statistics describe the spread of published results — a descriptive compilation, not a meta-analysis or a guarantee of plant yield.

Full methodology and correction policy

Bibliography

  1. Li, L.; Wang, R.; Jiang, Z.; Li, W.; Liu, G.; Chen, C. (2019). Anaerobic digestion of tobacco stalk: biomethane production performance and kinetic analysis. Environmental Science and Pollution Research 26(14), 14250–14258. DOI: 10.1007/s11356-019-04677-2 DOI
  2. Zhang, H.; Wang, L.; Dai, Z.; Zhang, R.; Chen, C.; Liu, G. (2020). Effect of organic loading, feed-to-inoculum ratio, and pretreatment on the anaerobic digestion of tobacco stalks. Bioresource Technology 298, 122474. DOI: 10.1016/j.biortech.2019.122474 DOI

All sources of the site: bibliography.