BMP testingWood and woody biomasssingle study (2 samples)

Wood residues from paper industry — BMP: 2 studies, weighted mean 144 m³ CH₄/t VS

Wood waste from the paper industry (bark, fine wood fractions) digests poorly because of the lignin; it was examined at 37 and 55 °C in a single study.

CH₄ ≈ 52 % (estimate)

Published Updated 3 min readFeedstockData Editorial Team

Photo Lee Lockwood / Wikimedia Commons, public domain, source file; changes: cropping

Weighted mean
144m³ CH₄/t VS
Range
116–171m³ CH₄/t VS
Records
2single study (2 samples)
Publications
1source
Temperatures
37 °C, 55 °Cof the test

Methane in biogas

Medium methane content · ≈ 5.2 kWh/m³ of biogas

estimate from the substrate type The collected studies contain no measurement. The interval follows from the approximate composition (carbohydrate-dominated (no protein or fat characteristics)) and the yields of compound groups according to FNR.

How we calculate it and what the zones mean

Rating for biogas plants

not rated — editorial rating for biogas plants

Not rated: no dry matter or volatile solids in the data. We calculate the rating when the dry matter and volatile solids of the material are known.

Editorial rating per the methodology

Add to the co-digestion calculator CSV data

BMP curves from 2 studies

Weighted mean Individual records

BMP curves: Wood residues from paper industryCumulative methane production over time for 2 records and the weighted mean of 144 m³ CH₄/t VS. 2 of the curves are model curves (first-order kinetics).0501001502000510152025303540time [d]m³ CH₄/t VSWalter et al. (2016) · 1: 116 m³ CH₄/t VS (model curve)Walter et al. (2016) · 2: 171 m³ CH₄/t VS (model curve)mean144

Dashed lines are a model curve (first-order kinetics, B(t) = B₀·(1 − e−kt)); the end point comes from the publication. All curves are model curves.

Cumulative methane production over the test [m³ CH₄/t VS]. The thick line is the weighted mean of all records (144); dots mark the end values given in the publications. Point at the chart to read values; click a legend item to hide or show a record.

Records and sources

Download CSV
SourceBMP
m³ CH₄/t VS
TemperatureSampleCurve
Walter et al. (2016) · 1 DOI11637 °C · mesophilicWood residues (WR), non-pretreated, 37 Cend point (model curve)
Walter et al. (2016) · 2 DOI17155 °C · thermophilicWood residues (WR), non-pretreated, 55 Cend point (model curve)
Weighted mean144arithmetic mean 144, SD 39

Process properties

  • fibrous
  • slowly degrading
  • carbon-rich
  • low in nitrogen
  • physical contaminants
  • variable composition
  • editorial classification

Advantages

  • Methane potential in the database: weighted mean 144 m³ CH₄/t VS (median 144; range 116–171; 2 records from 1 sources).

Drawbacks and risks

  • Spread of results in the database: standard deviation 39 at a mean of 144 m³ CH₄/t VS (2 records from 1 sources).

Co-digestion — what to combine it with, what to watch out for

Dosing

No source-based dose limits in co-digestion; add gradually and after a BMP test. The results relate to the specific streams described in Walter 2016.

Introduce gradually, starting with a small dose and monitoring the process (e.g. FOS/TAC, pH, gas composition).

Practical requirements

  • Shred: shredding increases the surface available for degradation and speeds it up, but does not necessarily raise the final gas yield (FNR 2010, Ch. 3 “Triturado”).
  • Remove foreign contaminants before dosing: material from biowaste may contain interfering substances, and the co-substrate should be free of them (FNR 2010, Ch. 3).

The co-digestion calculator will assess a specific mixture containing this substrate.

What it is and where it comes from

Wood waste from paper mills arises during the preparation of wood for pulp production: debarking, chipping and screening. It includes bark, fine chips, screening rejects and fine wood fractions. The dataset includes one study describing these wastes, without pretreatment, in tests at 37 °C and 55 °C. In paper mills such waste is usually sent for combustion in the mills' own boilers.

Properties relevant to digestion

The material consists of wood fibres and bark. Bark contains considerable amounts of lignin, tannins and other phenolic compounds, which can inhibit methanogenic bacteria. Cellulose is protected by lignin, so hydrolysis is slow. The low protein and nitrogen content gives a high C/N ratio, which requires supplementation with nitrogen in the mix. However, fine particles have a larger contact surface than coarse chips, which partly improves availability.

How to read the spread of results

The dataset consists of a small number of records from a single publication, differing in temperature, so the difference results mainly from the test conditions, not from different materials. More generally, the result is determined by the composition of the waste: the wood species, the share of bark, moisture and comminution, as well as the storage time, because during storage some of the readily available compounds are degraded or leached. The inoculum and the length of the experiment also have an effect.

In biogas plant practice

Wood waste from paper mills does not usually go to agricultural biogas plants. Combustion at the place of origin remains the better way of managing it. If digestion is considered, thorough comminution and a check for the presence of inhibitory compounds are necessary. The material is an industrial waste, and its acceptance requires an appropriate waste code and the installation's permit. The data are informational and do not justify planning an investment.

For comparison: biological sludges and fibre wastes from the same industry digest better than wood fractions and are therefore studied more often as substrates. Bark and fine wood are rather an energy waste of the plant, and only after pretreatment could they compete as a feedstock for digestion.

Before deciding on digestion, it is also worth measuring the moisture and the share of bark in the specific batch.

Methodology in brief

BMP is the amount of methane obtained from volatile solids (VS) in a batch test, given in m³ CH₄ per tonne of VS (numerically the same as NmL CH₄/g VS in the publications) and converted to normal conditions (0 °C, 101.325 kPa). The weighted mean gives each publication a total weight of 1, split equally between its results for the substrate — a paper testing twenty varieties does not outweigh a paper with a single sample. In inter-laboratory programmes the unit is the laboratory (total weight 1), and within it the weight of a test grows with the number of bottles (replicates). Results after pretreatment (e.g. thermal, chemical, enzymatic) are shown separately and are not included in the mean.

Solid lines are curves measured in the tests. Where a publication gives only the final result, we draw a first-order kinetic model, B(t) = B₀·(1 − e−kt): only the end point comes from the publication, and the shape of the curve serves purely as visualisation — do not read the production on a particular day from it. For this substrate k = 0.039 d−1 was assumed (median of rate constants k reported in the sources and/or fitted to the mean measured curves).

The statistics describe the spread of published results — a descriptive compilation, not a meta-analysis or a guarantee of plant yield.

Full methodology and correction policy

Bibliography

  1. Walter, A.; Silberberger, S.; Juárez, M.F.D.; Insam, H.; Franke-Whittle, I.H. (2016). Biomethane potential of industrial paper wastes and investigation of the methanogenic communities involved. Biotechnology for Biofuels 9(1), 21. DOI: 10.1186/s13068-016-0435-z DOI

All sources of the site: bibliography.